Tenure
According to a study in The Washington Post, Sununu voted with the Republican Party's position 84% of the time. However, he broke with his party on prominent issues, joining Democrats in filibusters of the USA PATRIOT Act and the Bush administration's 2003 energy bill. Sununu strongly supported greater access to firearms, voting against the proposed renewal of the 1994 Federal Assault Weapons Ban in 2004. In 2006, he voted against the Federal Marriage Amendment, a proposed constitutional amendment to ban gay marriage. He strongly opposed amnesty for illegal aliens, voting against the McCain-Kennedy immigration bill in July 2007. Sununu called for a tougher federal regulator for government-sponsored enterprises Fannie Mae and Freddie Mac, and with Senator Tim Johnson (D-SD), he filed a dramatic overhaul of regulation of the insurance industry. A long time proponent of technology, in January 2007, Sununu called for a permanent ban on taxes of Internet connections and online sales.
The non-partisan National Journal gave Sununu a composite rating of 65.8% conservative and 34% liberal in 2008. Sununu was one of only three senators whose voting record received a score of 100% from the fiscally conservative Club for Growth, in both 2005 and 2006, tying for 1st place. However, his rating fell to 23rd place in 2007, and to 34th place in 2008. The Club for Growth endorsed Sununu's unsuccessful bid for re-election in February 2007 against Jeanne Shaheen (she subsequently during 2009–2012 earned Club for Growth ratings of 64th place to 100th place).
In 2007, Sununu was the lead Republican co-sponsor of the Clean Air Planning Act of 2007 which sought to address air quality and climate change by establishing a schedule to reduce harmful emissions from power plants—in particular, sulfur dioxide and nitrogen oxides—as well as decrease carbon dioxide emissions through a cap and trade system. The legislation, which was never enacted, also addressed mercury pollution, calling for a 90% reduction in emissions of the chemical by 2015. He also supported the bipartisan Clean Energy Stimulus Act of 2008 that provides tax incentives for the development of clean and renewable energy sources. In 2006, Sununu sponsored the bipartisan New England Wilderness Act, which added tens of thousand of acres of land to federally protected forests. Sununu opposed the Climate Stewardship Act of 2003, which would have also created a cap-and-trade program. His vote was criticized by the New Hampshire Democratic Party which claimed that he had acted "against reducing greenhouse gases". The New Hampshire Union Leader praised his decision, citing the Energy Information Agency's estimation that the legislation would cost the American economy $507 billion over 22 years.
Sununu took a few positions contrary to the Bush administration and the Republican leadership. Although he voted for the flag-burning amendment, he voted against the Federal Marriage Amendment and he opposed restrictions on travel and trade with Cuba, and was one of only two Republicans to vote in favor of terminating funds for TV Martí, which broadcasts anti-Castro programming in Cuba. He was one of a small group of Republicans to vote in favor of banning loans to China for any nuclear projects, and in September 2005 he voted to disapprove a new rule set in place by the Administrator of the Environmental Protection Agency (EPA) delisting coal and other energy sources from the Clean Air Act.
He also became well known as one of the five Republican senators who joined Democrats in a filibuster of the USA PATRIOT Act renewal conference report, concerned about possible negative impacts the bill had on civil liberties. This caused the Republican leadership to extend the original legislation until a compromise bill was forged.
In January 2006, at a hearing in front of the Commerce, Science and Transportation Committee on the Broadcast Flag, Sununu was one of the very few present to criticize the legislation, saying "In all cases [of previous technological advancements in the US], we didn't need to step in with a significant statutory government-regulated mandate on technology that consumers use to enjoy this material".
In October 2006, Sununu voted against a portion of the Military Commissions Act of 2006 that would suspend the right of habeas corpus for non-citizen detainees. After voting in favor of the final bill, he defended his vote by telling reporters "The Constitution is not a suicide pact".
On March 14, 2007, Sununu became the first Republican senator to call for the firing of Attorney General Alberto Gonzales after a controversy over U.S. Attorney firings. Sununu cited his anger with the mismanagement by Gonzales and the lack of trustworthiness by GOP senators towards Gonzales.
In July 2005, Sununu shaved his head to show solidarity with Senator Arlen Specter, who had lost his hair due to chemotherapy for Hodgkin's disease.
In September 2008, Sununu became one of twenty senators (ten Democrats and ten Republicans) co-sponsoring a bipartisan energy bill, the New Energy Reform Act of 2008. The bill was offered as an alternative to the Democrats' energy bill, sponsored by House Speaker Nancy Pelosi. Both bills proposed to increase offshore drilling, while promoting conservation and alternative energy. The "Gang of Twenty" bill also lets coastal states participate in decisions and in revenue about drilling in the fifty-to-one-hundred-mile range off their coasts. It also differs from the Democrats' bill in allowing drilling off Florida's west coast, a proposal both Florida's senators have protested. To quote the Minneapolis Star Tribune, "Nearly every potentially vulnerable Senate Republican, from Norm Coleman [of Minnesota] to Elizabeth Dole of North Carolina and John Sununu of New Hampshire, has signed on to the legislation."